GaI3 [gallium(Ⅲ) iodide] has one gallium atom and three iodine atoms.
In GaI3 Lewis structure, there are three single bonds around the gallium atom, with three iodine atoms attached to it, and on each iodine atom, there are three lone pairs.
Steps
Here’s how you can easily draw the GaI3 Lewis structure step by step:
#1 Draw a rough skeleton structure
#2 Mention lone pairs on the atoms
#3 If needed, mention formal charges on the atoms
Now, let’s take a closer look at each step mentioned above.
#1 Draw a rough skeleton structure
- First, determine the total number of valence electrons
In the periodic table, gallium lies in group 13, and iodine lies in group 17.
Hence, gallium has three valence electrons and iodine has seven valence electrons.
Since GaI3 has one gallium atom and three iodine atoms, so…
Valence electrons of one gallium atom = 3 × 1 = 3
Valence electrons of three iodine atoms = 7 × 3 = 21
And the total valence electrons = 3 + 21 = 24
Learn how to find: Gallium valence electrons
- Second, find the total electron pairs
We have a total of 24 valence electrons. And when we divide this value by two, we get the value of total electron pairs.
Total electron pairs = total valence electrons ÷ 2
So the total electron pairs = 24 ÷ 2 = 12
- Third, determine the central atom
We have to place the least electronegative atom at the center.
Since gallium is less electronegative than iodine, assume that the central atom is gallium.
Therefore, place gallium in the center and iodines on either side.
- And finally, draw the rough sketch
#2 Mention lone pairs on the atoms
Here, we have a total of 12 electron pairs. And three Ga — I bonds are already marked. So we have to only mark the remaining nine electron pairs as lone pairs on the sketch.
Also remember that gallium is a period 4 element, so it can keep more than 8 electrons in its last shell. And iodine is a period 5 element, so it can keep more than 8 electrons in its last shell.
Always start to mark the lone pairs from outside atoms. Here, the outside atoms are iodines.
So for each iodine, there are three lone pairs, and for gallium, there is zero lone pair because all nine electron pairs are over.
Mark the lone pairs on the sketch as follows:
#3 If needed, mention formal charges on the atoms
Use the following formula to calculate the formal charges on atoms:
Formal charge = valence electrons – nonbonding electrons – ½ bonding electrons
For gallium atom, formal charge = 3 – 0 – ½ (6) = 0
For each iodine atom, formal charge = 7 – 6 – ½ (2) = 0
Here, both gallium and iodine atoms do not have charges, so no need to mark the charges.
In the above structure, you can see that the central atom (gallium) doesn’t form an octet. But, gallium has an exception that it does not require eight electrons to form an octet. So no need to worry about the octet rule here.
Therefore, this structure is the stable Lewis structure of GaI3.
Next: SeO42- Lewis structure
External links
- https://lambdageeks.com/gai3-lewis-structure/
- https://homework.study.com/explanation/draw-the-lewis-structure-for-gai3-and-provide-the-following-information-a-number-of-bonding-electron-pairs-b-number-of-nonbonding-electron-pairs-c-electron-geometry-d-molecular-geometry-e-approximate-bond-angle.html
- https://www.bartleby.com/questions-and-answers/for-the-molecule-gai3-give-the-lewis-structure-the-valence-shell-electron-pairs-the-bonding-electron/bf8a37ed-a3e5-4c28-9b40-910420926a2e
Deep
Learnool.com was founded by Deep Rana, who is a mechanical engineer by profession and a blogger by passion. He has a good conceptual knowledge on different educational topics and he provides the same on this website. He loves to learn something new everyday and believes that the best utilization of free time is developing a new skill.