BeF2 Lewis structure

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BeF2 Lewis Structure
BeF2 Lewis structure

BeF2 (beryllium fluoride) has one beryllium atom and two fluorine atoms.

In the BeF2 Lewis structure, there are two single bonds around the beryllium atom, with two fluorine atoms attached to it, and on each fluorine atom, there are three lone pairs.


Use these steps to correctly draw the BeF2 Lewis structure:

#1 First draw a rough sketch
#2 Mark lone pairs on the atoms
#3 Calculate and mark formal charges on the atoms, if required

Let’s discuss each step in more detail.

#1 First draw a rough sketch

  • First, determine the total number of valence electrons
Periodic table

In the periodic table, beryllium lies in group 2, and fluorine lies in group 17.

Hence, beryllium has two valence electrons and fluorine has seven valence electrons.

Since BeF2 has one beryllium atom and two fluorine atoms, so…

Valence electrons of one beryllium atom = 2 × 1 = 2
Valence electrons of two fluorine atoms = 7 × 2 = 14

And the total valence electrons = 2 + 14 = 16

  • Second, find the total electron pairs

We have a total of 16 valence electrons. And when we divide this value by two, we get the value of total electron pairs.

Total electron pairs = total valence electrons ÷ 2

So the total electron pairs = 16 ÷ 2 = 8

  • Third, determine the central atom

We have to place the least electronegative atom at the center.

Since beryllium is less electronegative than fluorine, assume that the central atom is beryllium.

Therefore, place beryllium in the center and fluorines on either side.

  • And finally, draw the rough sketch
BeF2 Lewis Structure (Step 1)
Rough sketch of BeF2 Lewis structure

#2 Mark lone pairs on the atoms

Here, we have a total of 8 electron pairs. And two Be — F bonds are already marked. So we have to only mark the remaining six electron pairs as lone pairs on the sketch.

Also remember that both (beryllium and fluorine) are the period 2 elements, so they can not keep more than 8 electrons in their last shell.

Always start to mark the lone pairs from outside atoms. Here, the outside atoms are fluorines.

So for each fluorine, there are three lone pairs, and for beryllium, there is zero lone pair because all six electron pairs are over.

Mark the lone pairs on the sketch as follows:

BeF2 Lewis Structure (Step 2)
Lone pairs marked, and got the stable Lewis structure of BeF2

#3 Calculate and mark formal charges on the atoms, if required

Use the following formula to calculate the formal charges on atoms:

Formal charge = valence electrons – nonbonding electrons – ½ bonding electrons

For beryllium atom, formal charge = 2 – 0 – ½ (4) = 0

For each fluorine atom, formal charge = 7 – 6 – ½ (2) = 0

Here, both beryllium and fluorine atoms do not have charges, so no need to mark the charges.

In the above structure, you can see that the central atom (beryllium) doesn’t form an octet. But, beryllium has an exception that it does not require eight electrons to form an octet. So no need to worry about the octet rule here.

Therefore, this structure is the stable Lewis structure of BeF2.

Next: OH Lewis structure

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