H3O+ Lewis Structure

H3O+ Lewis Structure

H3O+ (hydronium) has three hydrogen atoms and one oxygen atom. In the lewis structure of H3O+, there are three single bonds around the oxygen atom, with three hydrogen atoms attached to it, and on the oxygen atom, there is one lone pair.

Also, there is a positive (+1) charge on the oxygen atom.

Steps

Here’s how you can draw the H3O+ lewis structure step by step.

Step #1: draw sketch
Step #2: mark lone pairs
Step #3: mark charges (if there are)

Let’s break down each step in detail.

#1 Draw Sketch

  • First, determine the total number of valence electrons

In the periodic table, hydrogen lies in group 1, and oxygen lies in group 16.

Hence, hydrogen has one valence electron and oxygen has six valence electrons.

Since H3O+ has three hydrogen atoms and one oxygen atom, so…

Valence electrons of three hydrogen atoms = 1 × 3 = 3
Valence electrons of one oxygen atom = 6 × 1 = 6

Now the H3O+ has a positive (+1) charge, so we have to subtract one electron.

So the total valence electrons = 3 + 6 – 1 = 8

  • Second, find the total electron pairs

We have a total of 8 valence electrons. And when we divide this value by two, we get the value of total electron pairs.

Total electron pairs = total valence electrons ÷ 2

So the total electron pairs = 8 ÷ 2 = 4

  • Third, determine the central atom

Here hydrogen can not be the central atom. Because the central atom is bonded with at least two other atoms, and hydrogen has only one electron in its last shell, so it can not make more than one bond.

Hence, here we have to assume that the central atom is oxygen.

Therefore, place oxygen in the center and hydrogens on either side.

  • And finally, draw the rough sketch
H3O+ Lewis Structure (Step 1)

#2 Mark Lone Pairs

Here, we have a total of 4 electron pairs. And three O — H bonds are already marked. So we have to only mark the remaining one electron pair as a lone pair on the sketch.

Also remember that hydrogen is a period 1 element, so it can not keep more than 2 electrons in its last shell. And oxygen is a period 2 element, so it can not keep more than 8 electrons in its last shell.

Always start to mark the lone pairs from outside atoms. Here, the outside atoms are hydrogens. But no need to mark on hydrogen, because each hydrogen has already two electrons.

So for oxygen, there is one lone pair.

Mark the lone pair on the sketch as follows:

H3O+ Lewis Structure (Step 2)

#3 Mark Charges

Use the following formula to calculate the formal charges on atoms:

Formal charge = valence electrons – nonbonding electrons – ½ bonding electrons

For each hydrogen atom, formal charge = 1 – 0 – ½ (2) = 0

For oxygen atom, formal charge = 6 – 2 – ½ (6) = +1

Here, the oxygen atom has a charge, so mark it on the sketch as follows:

H3O+ Lewis Structure (Step 3)

In the above structure, you can see that the central atom (oxygen) forms an octet. Hence, the octet rule is satisfied.

Therefore, this structure is the most stable lewis structure of H3O+.

And since the H3O+ has a positive (+1) charge, mention that charge on the lewis structure by drawing brackets as follows:

H3O+ Lewis Structure (Final)

Next: CH3NO2 Lewis Structure

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