SiF4 Lewis structure

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SiF4 Lewis Structure
SiF4 Lewis structure

SiF4 (silicon tetrafluoride) has one silicon atom and four fluorine atoms.

In the SiF4 Lewis structure, there are four single bonds around the silicon atom, with four fluorine atoms attached to it, and on each fluorine atom, there are three lone pairs.


To properly draw the SiF4 Lewis structure, follow these steps:

#1 Draw a rough sketch of the structure
#2 Next, indicate lone pairs on the atoms
#3 Indicate formal charges on the atoms, if necessary

Let’s break down each step in more detail.

#1 Draw a rough sketch of the structure

  • First, determine the total number of valence electrons
Periodic table

In the periodic table, silicon lies in group 14, and fluorine lies in group 17.

Hence, silicon has four valence electrons and fluorine has seven valence electrons.

Since SiF4 has one silicon atom and four fluorine atoms, so…

Valence electrons of one silicon atom = 4 × 1 = 4
Valence electrons of four fluorine atoms = 7 × 4 = 28

And the total valence electrons = 4 + 28 = 32

  • Second, find the total electron pairs

We have a total of 32 valence electrons. And when we divide this value by two, we get the value of total electron pairs.

Total electron pairs = total valence electrons ÷ 2

So the total electron pairs = 32 ÷ 2 = 16

  • Third, determine the central atom

We have to place the least electronegative atom at the center.

Since silicon is less electronegative than fluorine, assume that the central atom is silicon.

Therefore, place silicon in the center and fluorines on either side.

  • And finally, draw the rough sketch
SiF4 Lewis Structure (Step 1)
Rough sketch of SiF4 Lewis structure

#2 Next, indicate lone pairs on the atoms

Here, we have a total of 16 electron pairs. And four Si — F bonds are already marked. So we have to only mark the remaining twelve electron pairs as lone pairs on the sketch.

Also remember that silicon is a period 3 element, so it can keep more than 8 electrons in its last shell. And fluorine is a period 2 element, so it can not keep more than 8 electrons in its last shell.

Always start to mark the lone pairs from outside atoms. Here, the outside atoms are fluorines.

So for each fluorine, there are three lone pairs, and for silicon, there is zero lone pair because all twelve electron pairs are over.

Mark the lone pairs on the sketch as follows:

SiF4 Lewis Structure (Step 2)
Lone pairs marked, and got the stable Lewis structure of SiF4

#3 Indicate formal charges on the atoms, if necessary

Use the following formula to calculate the formal charges on atoms:

Formal charge = valence electrons – nonbonding electrons – ½ bonding electrons

For silicon atom, formal charge = 4 – 0 – ½ (8) = 0

For each fluorine atom, formal charge = 7 – 6 – ½ (2) = 0

Here, both silicon and fluorine atoms do not have charges, so no need to mark the charges.

In the above structure, you can see that the central atom (silicon) forms an octet. And the outside atoms (fluorines) also form an octet. Hence, the octet rule is satisfied.

Therefore, this structure is the stable Lewis structure of SiF4.

Next: CH3F Lewis structure

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Deep was founded by Deep Rana, who is a mechanical engineer by profession and a blogger by passion. He has a good conceptual knowledge on different educational topics and he provides the same on this website. He loves to learn something new everyday and believes that the best utilization of free time is developing a new skill.

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