Europium

Europium
Europium block

Europium (Eu) is a chemical element of the periodic table, located in the period 6, and has the atomic number 63. It is the seventh element in the lanthanide series. It is a soft, silvery-white metal, which is named after Europe. It is the softest and the most reactive element in the lanthanide series and is counted as one of the rare earth elements.

On periodic table

group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
period
1 1
H
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Hydrogen
2
He
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Helium
2 3
Li
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Lithium
4
Be
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Beryllium
5
B
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Boron
6
C
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Carbon
7
N
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Nitrogen
8
O
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Oxygen
9
F
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Fluorine
10
Ne
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Neon
3 11
Na
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Sodium
12
Mg
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Magnesium
13
Al
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Aluminium
14
Si
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Silicon
15
P
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Phosphorus
16
S
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Sulfur
17
Cl
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Chlorine
18
Ar
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Argon
4 19
K
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Potassium
20
Ca
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Calcium
21
Sc
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Scandium
22
Ti
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Titanium
23
V
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Vanadium
24
Cr
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Chromium
25
Mn
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Manganese
26
Fe
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Iron
27
Co
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Cobalt
28
Ni
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Nickel
29
Cu
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Copper
30
Zn
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Zinc
31
Ga
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Gallium
32
Ge
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Germanium
33
As
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Arsenic
34
Se
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Selenium
35
Br
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Bromine
36
Kr
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Krypton
5 37
Rb
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Rubidium
38
Sr
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Strontium
39
Y
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Yttrium
40
Zr
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Zirconium
41
Nb
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Niobium
42
Mo
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Molybdenum
43
Tc
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Technetium
44
Ru
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Ruthenium
45
Rh
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Rhodium
46
Pd
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Palladium
47
Ag
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Silver
48
Cd
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Cadmium
49
In
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Indium
50
Sn
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Tin
51
Sb
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Antimony
52
Te
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Tellurium
53
I
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Iodine
54
Xe
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Xenon
6 55
Cs
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Caesium
56
Ba
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Barium
72
Hf
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Hafnium
73
Ta
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Tantalum
74
W
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Tungsten
75
Re
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Rhenium
76
Os
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Osmium
77
Ir
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Iridium
78
Pt
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Platinum
79
Au
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Gold
80
Hg
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Mercury
81
Tl
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Thallium
82
Pb
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Lead
83
Bi
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Bismuth
84
Po
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Polonium
85
At
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Astatine
86
Rn
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Radon
7 87
Fr
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Francium
88
Ra
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Radium
104
Rf
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Rutherfordium
105
Db
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Dubnium
106
Sg
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Seaborgium
107
Bh
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Bohrium
108
Hs
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Hassium
109
Mt
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Meitnerium
110
Ds
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Darmstadtium
111
Rg
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Roentgenium
112
Cn
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Copernicium
113
Nh
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Nihonium
114
Fl
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Flerovium
115
Mc
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Moscovium
116
Lv
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Livermorium
117
Ts
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Tennessine
118
Og
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Oganesson
57
La
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Lanthanum
58
Ce
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Cerium
59
Pr
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Praseodymium
60
Nd
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Neodymium
61
Pm
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Promethium
62
Sm
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Samarium
63
Eu
Europium
64
Gd
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Gadolinium
65
Tb
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Terbium
66
Dy
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Dysprosium
67
Ho
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Holmium
68
Er
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Erbium
69
Tm
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Thulium
70
Yb
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Ytterbium
71
Lu
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Lutetium
89
Ac
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Actinium
90
Th
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Thorium
91
Pa
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Protactinium
92
U
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Uranium
93
Np
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Neptunium
94
Pu
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Plutonium
95
Am
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Americium
96
Cm
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Curium
97
Bk
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Berkelium
98
Cf
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Californium
99
Es
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Einsteinium
100
Fm
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Fermium
101
Md
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Mendelevium
102
No
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Nobelium
103
Lr
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Lawrencium
– f block

Europium (Eu) is located on the periodic table in the lanthanide series, which is a group of elements located at the bottom of the table. Specifically, in period 6, between samarium (Sm) and gadolinium (Gd).

Element information

Europium Element
Europium appearance | source: Wikipedia
Europium Periodic Table
Europium location on periodic table
Europium is found in the sixth row of the periodic table, next to the samarium element.
Origin of name named after Europe
Symbol Eu
Atomic number (Z) 63
Atomic mass 151.964 u
Block f-block
Period 6
Classification Lanthanide
Atomic radius 180 pm
Covalent radius 198±6 pm
Melting point 826 ℃, 1519 ℉, 1099 K
Boiling point 1802 ℃, 2784 ℉, 1802 K
Electron configuration [Xe] 4f7 6s2
Electrons per shell 2, 8, 18, 25, 8, 2
Learn how to draw: Europium Bohr model
Crystal structure Body-centered cubic (bcc)
Phase at r.t Solid
Density near r.t 5.244 g/cm3
Main isotopes Europium-153
Natural occurrence Primordial
Oxidation state +2, +3
Electronegativity (Pauling scale) 1.2
Protons
Neutrons
Electrons
63
89
63
Learn how to find: Europium protons neutrons electrons
CAS number 7440-53-1
Discovered by Eugène-Anatole Demarçay in 1901

History

Eugène-Anatole Demarçay | source: Wikipedia

Europium, a rare earth element, was first known to chemists in the late 1800s. It wasn’t until 1892 that French chemist Paul Émile Lecoq de Boisbaudran obtained basic fractions from samarium-gadolinium concentrates with spectral lines that couldn’t be attributed to either samarium or gadolinium. However, Eugène-Anatole Demarçay, another French chemist, is generally credited with discovering europium. In 1896, Demarçay observed some contamination while studying samples of samarium, which led him to suspect the presence of an unknown element. He successfully isolated the new element in 1901 and named it “europium” after the continent Europe.

The discovery of europium proved to be of great importance in the color television industry, which was just starting to emerge in the early 1960s. At the time, the red phosphor used in color TV screens was very weak, and the other phosphor colors had to be muted to maintain color balance. However, the discovery of the europium-doped yttrium orthovanadate red phosphor led to a brighter color TV picture, as it was no longer necessary to mute the other colors. As a result, there was a scramble for the limited supply of europium, with monazite processors competing for the rare element. Europium has continued to be used in the TV industry and computer monitors since then.

Europium has an interesting history, with chemists and scientists discovering its properties and potential applications over time. One story, related by Frank Spedding, a celebrated chemist, involved an elderly gentleman who approached him with an offer of several pounds of europium oxide. Spedding did not take the man seriously, but a package eventually arrived in the mail containing several pounds of genuine europium oxide. The elderly gentleman turned out to be Herbert Newby McCoy, who had developed a famous method of europium purification involving redox chemistry. This is just one example of the many contributions and discoveries that have been made in the study of europium over the years.

Occurrence and production

Europium is a rare earth element and is relatively abundant in the Earth’s crust. It is found in minerals such as monazite, bastnäsite, xenotime, and loparite. Monazite is the most important source of europium, with typical europium content of about 0.05%. Bastnäsite from the Mountain Pass mine in California, USA, has an unusually high europium content of about 0.1%, while the Bayan Obo mine in China has an even richer europium content of 0.2%.

The production of europium involves several steps, including mining, extraction, and purification. The primary source of europium is the mineral monazite, which is typically extracted through the process of acid cracking, followed by solvent extraction or ion exchange to separate the rare earth elements. The purified rare earth elements are then further processed through a series of chemical reactions to obtain europium metal or its oxide.

Europium is produced on a relatively small scale compared to other rare earth elements due to its low abundance and the difficulty of separating it from other rare earth elements. The largest producers of europium are currently China, the United States, and Brazil, with smaller amounts produced by other countries including India, Australia, and Russia. Europium is used primarily in the production of color phosphors for television and computer screens, as well as in nuclear reactors and certain types of lighting.

Properties

Europium is a soft, silvery-white metal that tarnishes quickly in air.

Europium is a rare earth metal that is moderately hard, malleable, and ductile, which means it can be easily shaped into thin sheets or drawn into wires.

It has a relatively low melting point and boiling point compared to most metals.

Europium is chemically reactive, particularly in its metallic state, and it readily forms compounds with oxygen, water, and acids.

Europium is a paramagnetic element, meaning it is weakly attracted to a magnetic field.

It has two stable isotopes, Eu-151 and Eu-153, with Eu-153 being slightly more abundant.

Europium has a unique red fluorescence that is used in the production of certain types of lighting and color displays.

Applications

Europium is commonly used as an activator in phosphors, which are materials that emit light in response to certain stimuli such as electron bombardment. In particular, europium is used in red and blue phosphors for color displays, including those used in computer monitors, televisions, and mobile devices.

Europium is used as a neutron absorber in nuclear reactors to help control the rate of nuclear fission. Specifically, europium-153 is used in the control rods of some reactors.

Europium is used as an activator in metal halide lamps, which are a type of high-intensity discharge lamp used for indoor and outdoor lighting. These lamps are known for their high efficiency, long life, and high color rendering index.

Europium is one of the rare earth elements that has unique magnetic properties. It is used in the production of high-performance magnets, including those used in computer hard drives and other electronic devices.

Europium is used in the production of special glasses and ceramics that have unique optical properties. For example, europium-doped glass can be used as a radiation detector, while europium-doped ceramics can be used as scintillators for medical imaging.

Interesting facts

Europium is the most reactive of the rare earth elements.

It is a good absorber of neutrons and is used in the control rods of nuclear reactors.

Europium is the only rare earth element that has a stable isotope, which makes it useful in nuclear magnetic resonance (NMR) studies.

Its unique fluorescence properties have been used to authenticate banknotes and passports.

The red and blue phosphors based on europium are used in television and computer screens.

Europium was discovered by a French chemist, Eugène-Anatole Demarçay, in 1896 while analyzing the spectral lines of samarium.

Related

More elements

s block
p block
d block
f block
Barium Aluminium Bohrium Actinium
Beryllium Antimony Cadmium Americium
Caesium Argon Chromium Berkelium
Calcium Arsenic Cobalt Californium
Francium Astatine Copernicium Cerium
Helium Bismuth Copper Curium
Hydrogen Boron Darmstadtium Dysprosium
Lithium Bromine Dubnium Einsteinium
Magnesium Carbon Gold Erbium
Potassium Chlorine Hafnium Europium
Radium Flerovium Hassium Fermium
Rubidium Fluorine Iridium Gadolinium
Sodium Gallium Iron Holmium
Strontium Germanium Lawrencium Lanthanum
Indium Lutetium Mendelevium
Iodine Manganese Neodymium
Krypton Meitnerium Neptunium
Lead Mercury Nobelium
Livermorium Molybdenum Plutonium
Moscovium Nickel Praseodymium
Neon Niobium Promethium
Nihonium Osmium Protactinium
Nitrogen Palladium Samarium
Oganesson Platinum Terbium
Oxygen Rhenium Thorium
Phosphorus Rhodium Thulium
Polonium Roentgenium Uranium
Radon Ruthenium Ytterbium
Selenium Rutherfordium
Silicon Scandium
Sulfur Seaborgium
Tellurium Silver
Tennessine Tantalum
Thallium Technetium
Tin Titanium
Xenon Tungsten
Vanadium
Yttrium
Zinc
Zirconium

External links

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Learnool.com was founded by Deep Rana, who is a mechanical engineer by profession and a blogger by passion. He has a good conceptual knowledge on different educational topics and he provides the same on this website. He loves to learn something new everyday and believes that the best utilization of free time is developing a new skill.

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