Lanthanum

Lanthanum
Lanthanum block

Lanthanum (La) is a chemical element of the periodic table, located in the period 6, and has the atomic number 57. It is the first element in the lanthanide series. It is a soft, silvery-white metal, whose name comes from the Greek word “lanthanein”, which means to lie hidden. It is a highly reactive metal and is counted as one of the rare earth elements.

On periodic table

group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
period
1 1
H
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Hydrogen
2
He
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Helium
2 3
Li
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Lithium
4
Be
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Beryllium
5
B
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Boron
6
C
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Carbon
7
N
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Nitrogen
8
O
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Oxygen
9
F
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Fluorine
10
Ne
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Neon
3 11
Na
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Sodium
12
Mg
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Magnesium
13
Al
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Aluminium
14
Si
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Silicon
15
P
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Phosphorus
16
S
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Sulfur
17
Cl
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Chlorine
18
Ar
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Argon
4 19
K
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Potassium
20
Ca
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Calcium
21
Sc
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Scandium
22
Ti
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Titanium
23
V
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Vanadium
24
Cr
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Chromium
25
Mn
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Manganese
26
Fe
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Iron
27
Co
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Cobalt
28
Ni
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Nickel
29
Cu
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Copper
30
Zn
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Zinc
31
Ga
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Gallium
32
Ge
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Germanium
33
As
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Arsenic
34
Se
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Selenium
35
Br
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Bromine
36
Kr
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Krypton
5 37
Rb
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Rubidium
38
Sr
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Strontium
39
Y
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Yttrium
40
Zr
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Zirconium
41
Nb
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Niobium
42
Mo
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Molybdenum
43
Tc
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Technetium
44
Ru
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Ruthenium
45
Rh
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Rhodium
46
Pd
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Palladium
47
Ag
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Silver
48
Cd
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Cadmium
49
In
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Indium
50
Sn
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Tin
51
Sb
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Antimony
52
Te
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Tellurium
53
I
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Iodine
54
Xe
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Xenon
6 55
Cs
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Caesium
56
Ba
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Barium
72
Hf
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Hafnium
73
Ta
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Tantalum
74
W
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Tungsten
75
Re
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Rhenium
76
Os
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Osmium
77
Ir
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Iridium
78
Pt
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Platinum
79
Au
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Gold
80
Hg
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Mercury
81
Tl
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Thallium
82
Pb
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Lead
83
Bi
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Bismuth
84
Po
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Polonium
85
At
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Astatine
86
Rn
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Radon
7 87
Fr
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Francium
88
Ra
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Radium
104
Rf
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Rutherfordium
105
Db
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Dubnium
106
Sg
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Seaborgium
107
Bh
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Bohrium
108
Hs
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Hassium
109
Mt
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Meitnerium
110
Ds
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Darmstadtium
111
Rg
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Roentgenium
112
Cn
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Copernicium
113
Nh
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Nihonium
114
Fl
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Flerovium
115
Mc
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Moscovium
116
Lv
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Livermorium
117
Ts
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Tennessine
118
Og
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Oganesson
57
La
Lanthanum
58
Ce
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Cerium
59
Pr
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Praseodymium
60
Nd
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Neodymium
61
Pm
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Promethium
62
Sm
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Samarium
63
Eu
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Europium
64
Gd
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Gadolinium
65
Tb
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Terbium
66
Dy
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Dysprosium
67
Ho
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Holmium
68
Er
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Erbium
69
Tm
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Thulium
70
Yb
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Ytterbium
71
Lu
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Lutetium
89
Ac
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Actinium
90
Th
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Thorium
91
Pa
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Protactinium
92
U
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Uranium
93
Np
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Neptunium
94
Pu
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Plutonium
95
Am
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Americium
96
Cm
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Curium
97
Bk
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Berkelium
98
Cf
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Californium
99
Es
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Einsteinium
100
Fm
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Fermium
101
Md
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Mendelevium
102
No
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Nobelium
103
Lr
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Lawrencium
– f block

Lanthanum (La) is located on the periodic table in the lanthanide series, which is a group of elements located at the bottom of the table. Specifically, in period 6, next to barium (Ba).

Element information

Lanthanum Element
Lanthanum appearance | source: Wikipedia
Lanthanum Periodic Table
Lanthanum location on periodic table
Lanthanum is found in the sixth row of the periodic table, next to the barium element.
Origin of name Greek word “lanthanein” (which means to lie hidden)
Symbol La
Atomic number (Z) 57
Atomic mass 138.90547 u
Block f-block
Period 6
Classification Lanthanide
Atomic radius 187 pm
Covalent radius 207±8 pm
Melting point 920 ℃, 1688 ℉, 1193 K
Boiling point 3464 ℃, 6267 ℉, 3737 K
Electron configuration [Xe] 5d1 6s2
Electrons per shell 2, 8, 18, 18, 9, 2
Crystal structure Double hexagonal close-packed (dhcp)
Phase at r.t Solid
Density near r.t 6.162 g/cm3
Main isotopes Lanthanum-139
Natural occurrence Primordial
Oxidation state +3
Electronegativity (Pauling scale) 1.10
Protons
Neutrons
Electrons
57
82
57
CAS number 7439-91-0
Discovered by Carl Gustaf Mosander in 1839

History

Carl Gustaf Mosander | source: Wikipedia

Lanthanum is a member of the lanthanide series and is named after the Greek word for “to lie hidden.” Lanthanum was first discovered in 1839 by the Swedish chemist Carl Gustaf Mosander, who extracted it from cerium nitrate.

Mosander was studying the mineral cerite, which had been discovered earlier in Sweden. He found that cerite contained several different rare earth elements, including lanthanum oxide. Mosander was able to isolate lanthanum oxide by treating cerite with nitric acid and then precipitating the lanthanum with oxalic acid.

After its discovery, lanthanum remained a relatively obscure element until the late 19th century, when chemists began to explore the properties of the rare earth elements more thoroughly. In the early 20th century, lanthanum found use in the manufacture of gas lantern mantles and was also used in the production of ferrocerium, a material used to create sparks in lighters and other devices.

Today, lanthanum is still used in the production of ferrocerium, as well as in the manufacture of nickel-metal hydride batteries, which are used in hybrid and electric vehicles. It is also used in the production of high-refractive-index glass, such as the lenses used in cameras and telescopes.

Occurrence and production

Lanthanum is a relatively abundant element, ranking as the 28th most abundant element in the Earth’s crust. It is found in a number of minerals, including monazite and bastnasite. Monazite is the most common source of lanthanum, and is primarily found in India, Brazil, and South Africa. Bastnasite, on the other hand, is found mainly in the United States, China, and Australia.

The production of lanthanum involves the extraction of lanthanum-containing minerals, which are then processed to obtain pure lanthanum metal. The primary method of extraction is through solvent extraction, where the mineral concentrate is dissolved in acid and then treated with organic solvents to separate the lanthanum from other rare earth metals. The resulting lanthanum compound is then heated with a reducing agent to produce pure lanthanum metal.

Lanthanum is also produced as a byproduct of the extraction of other rare earth elements, such as cerium and neodymium. In this case, the lanthanum is extracted from the waste material produced during the processing of these other elements.

Properties

Lanthanum is a silvery-white, malleable and ductile metal.

It has a relatively low melting point of 920 ℃ and a boiling point of 3464 ℃.

It is highly reactive and can quickly tarnish in air, forming a protective oxide layer that prevents further oxidation.

Lanthanum is paramagnetic, meaning it can be weakly magnetized when exposed to a magnetic field.

Lanthanum is a relatively soft metal and can be easily cut with a knife.

Applications

Lanthanum oxide is an important component of high-performance ceramics used in electronics, communication devices, and thermal barrier coatings.

Lanthanum carbonate is used as a material for the gas lantern mantles because of its ability to emit a bright light when heated.

Lanthanum-nickel-hydride batteries are used in electric vehicles and hybrid cars.

Lanthanum compounds are used as catalysts in the cracking process of petroleum refining.

Lanthanum oxide is used as a component of optical glasses due to its high refractive index.

Small amounts of lanthanum are added to steel to improve its strength and ductility.

Lanthanum-containing contrast agents are used in MRI imaging.

Interesting facts

Lanthanum was named after the Greek word “lanthanein” which means “to lie hidden”, as it is a rare earth metal that is not found in large quantities in the Earth’s crust.

Lanthanum is the first element in the lanthanide series of elements, which includes all the rare earth metals.

Lanthanum is a soft, malleable, and ductile metal that can be easily cut with a knife. It has a silvery-white appearance that tarnishes quickly when exposed to air.

Lanthanum is used in the production of high-intensity carbon arc lamps, which are used for movie projectors and studio lighting. It is also used in other types of lamps, such as incandescent lamps and fluorescent lamps.

Lanthanum is added to steel and iron to improve their strength, hardness, and ductility. It is also used in other alloys, such as nickel-metal hydride batteries, which are used in hybrid vehicles and other applications.

Lanthanum is a component of catalysts used in the refining of crude oil and in the production of gasoline. It is also used as a catalyst in the production of plastics and synthetic fibers.

Lanthanum has no known biological role and is considered to be toxic to humans and other animals.

Related

More elements

s block
p block
d block
f block
Barium Aluminium Bohrium Actinium
Beryllium Antimony Cadmium Americium
Caesium Argon Chromium Berkelium
Calcium Arsenic Cobalt Californium
Francium Astatine Copernicium Cerium
Helium Bismuth Copper Curium
Hydrogen Boron Darmstadtium Dysprosium
Lithium Bromine Dubnium Einsteinium
Magnesium Carbon Gold Erbium
Potassium Chlorine Hafnium Europium
Radium Flerovium Hassium Fermium
Rubidium Fluorine Iridium Gadolinium
Sodium Gallium Iron Holmium
Strontium Germanium Lawrencium Lanthanum
Indium Lutetium Mendelevium
Iodine Manganese Neodymium
Krypton Meitnerium Neptunium
Lead Mercury Nobelium
Livermorium Molybdenum Plutonium
Moscovium Nickel Praseodymium
Neon Niobium Promethium
Nihonium Osmium Protactinium
Nitrogen Palladium Samarium
Oganesson Platinum Terbium
Oxygen Rhenium Thorium
Phosphorus Rhodium Thulium
Polonium Roentgenium Uranium
Radon Ruthenium Ytterbium
Selenium Rutherfordium
Silicon Scandium
Sulfur Seaborgium
Tellurium Silver
Tennessine Tantalum
Thallium Technetium
Tin Titanium
Xenon Tungsten
Vanadium
Yttrium
Zinc
Zirconium

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