Osmium

Osmium
Osmium block | Image: Learnool

Osmium (Os) is a chemical element of the periodic table, located in the group 8 and the period 6, and is having the atomic number 76. It is a hard, rare, brittle, lustrous, bluish-white transition metal, whose name comes from the Greek word “osme”, which means smell.

On periodic table

group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
period
1 1
H
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Hydrogen
2
He
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Helium
2 3
Li
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Lithium
4
Be
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Beryllium
5
B
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Boron
6
C
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Carbon
7
N
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Nitrogen
8
O
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Oxygen
9
F
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Fluorine
10
Ne
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Neon
3 11
Na
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Sodium
12
Mg
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Magnesium
13
Al
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Aluminium
14
Si
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Silicon
15
P
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Phosphorus
16
S
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Sulfur
17
Cl
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Chlorine
18
Ar
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Argon
4 19
K
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Potassium
20
Ca
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Calcium
21
Sc
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Scandium
22
Ti
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Titanium
23
V
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Vanadium
24
Cr
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Chromium
25
Mn
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Manganese
26
Fe
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Iron
27
Co
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Cobalt
28
Ni
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Nickel
29
Cu
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Copper
30
Zn
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Zinc
31
Ga
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Gallium
32
Ge
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Germanium
33
As
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Arsenic
34
Se
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Selenium
35
Br
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Bromine
36
Kr
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Krypton
5 37
Rb
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Rubidium
38
Sr
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Strontium
39
Y
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Yttrium
40
Zr
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Zirconium
41
Nb
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Niobium
42
Mo
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Molybdenum
43
Tc
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Technetium
44
Ru
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Ruthenium
45
Rh
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Rhodium
46
Pd
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Palladium
47
Ag
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Silver
48
Cd
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Cadmium
49
In
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Indium
50
Sn
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Tin
51
Sb
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Antimony
52
Te
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Tellurium
53
I
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Iodine
54
Xe
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Xenon
6 55
Cs
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Caesium
56
Ba
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Barium
72
Hf
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Hafnium
73
Ta
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Tantalum
74
W
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Tungsten
75
Re
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Rhenium
76
Os
Osmium
77
Ir
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Iridium
78
Pt
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Platinum
79
Au
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Gold
80
Hg
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Mercury
81
Tl
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Thallium
82
Pb
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Lead
83
Bi
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Bismuth
84
Po
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Polonium
85
At
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Astatine
86
Rn
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Radon
7 87
Fr
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Francium
88
Ra
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Radium
104
Rf
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Rutherfordium
105
Db
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Dubnium
106
Sg
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Seaborgium
107
Bh
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Bohrium
108
Hs
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Hassium
109
Mt
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Meitnerium
110
Ds
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Darmstadtium
111
Rg
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Roentgenium
112
Cn
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Copernicium
113
Nh
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Nihonium
114
Fl
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Flerovium
115
Mc
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Moscovium
116
Lv
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Livermorium
117
Ts
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Tennessine
118
Og
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Oganesson
57
La
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Lanthanum
58
Ce
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Cerium
59
Pr
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Praseodymium
60
Nd
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Neodymium
61
Pm
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Promethium
62
Sm
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Samarium
63
Eu
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Europium
64
Gd
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Gadolinium
65
Tb
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Terbium
66
Dy
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Dysprosium
67
Ho
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Holmium
68
Er
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Erbium
69
Tm
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Thulium
70
Yb
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Ytterbium
71
Lu
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Lutetium
89
Ac
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Actinium
90
Th
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Thorium
91
Pa
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Protactinium
92
U
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Uranium
93
Np
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Neptunium
94
Pu
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Plutonium
95
Am
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Americium
96
Cm
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Curium
97
Bk
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Berkelium
98
Cf
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Californium
99
Es
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Einsteinium
100
Fm
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Fermium
101
Md
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Mendelevium
102
No
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Nobelium
103
Lr
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Lawrencium
– d block

Osmium is a d-block element, situated in the eighth column and the sixth row of the periodic table, denoted by the atomic number 76 and chemical symbol Os.

Element information

Osmium Element
Osmium appearance | Image: Wikipedia
Osmium Periodic Table
Osmium location on periodic table | Image: Learnool
Osmium is found in the eighth column of the periodic table, next to the rhenium element.
Origin of name Greek word “osme” (which means smell)
Symbol Os
Atomic number (Z) 76
Atomic mass 190.23 u
Block d-block
Group 8
Period 6
Classification Transition metal
Atomic radius 135 pm
Covalent radius 144±4 pm
Melting point 3033 ℃, 5491 ℉, 3306 K
Boiling point 5012 ℃, 9054 ℉, 5285 K
Electron configuration [Xe] 4f14 5d6 6s2
Learn how to write: Osmium electron configuration
Electrons per shell 2, 8, 18, 32, 14, 2
Crystal structure Hexagonal close-packed (hcp)
Phase at r.t Solid
Density near r.t 22.59 g/cm3
Main isotopes Osmium-187, Osmium-188, Osmium-189, Osmium-190, Osmium-192
Natural occurrence Primordial
Oxidation state +4
Electronegativity (Pauling scale) 2.2
Protons
Neutrons
Electrons
76
114
76
Learn how to find: Osmium protons neutrons electrons
CAS number 7440-04-2
Discovered by Smithson Tennant in 1803

History

Smithson Tennant | Image: WorldOfChemicals

Osmium was discovered in 1803 by English chemist Smithson Tennant. Tennant was examining the residues left after dissolving platinum in nitrohydrochloric acid and discovered a black residue that resisted attack by acids and alkalis. He identified this substance as a new element, which he named “osmium” after the Greek word “osme,” meaning “smell,” because of the strong smell of the volatile osmium tetroxide compound produced when osmium is heated.

However, it was not until the mid-1800s that the properties of osmium were more fully investigated. In 1844, Swedish chemist Carl Gustaf Mosander succeeded in separating osmium from other platinum metals, and in 1860, English chemist Thomas Andrews was the first to determine the density of osmium, which is the densest naturally occurring element. Since its discovery, osmium has been found in platinum ores and also in river sands in the Urals and North America.

Occurrence and production

Osmium is a rare and highly dense metal that occurs naturally in the Earth’s crust. It is one of the least abundant elements in the Earth’s crust and is usually found as a trace element in ores of other metals such as nickel, copper, and platinum. The largest producers of osmium are Russia, Canada, and South Africa.

Osmium is typically produced as a byproduct of nickel or copper refining, with most of the world’s osmium coming from nickel mines in the Sudbury Basin in Canada and the Norilsk region in Russia. The metal is extracted from the residues of the refining process by dissolving it in sodium peroxide, which converts the osmium to the more soluble osmium tetroxide. The osmium tetroxide can then be reduced with hydrogen gas to produce pure osmium metal.

Properties

Osmium is a hard, brittle, dense, silvery-white transition metal that is part of the platinum group metals.

It has a high melting point of 3033 ℃ and a boiling point of 5012 ℃, which are the highest of all the elements.

Osmium is also extremely dense, with a density of 22.59 g/cm3, making it the densest naturally occurring element.

It has a very low electrical resistance and is a good conductor of heat and electricity.

Osmium is also highly resistant to corrosion, making it useful in various applications, including as an alloying agent with other metals to improve their hardness and resistance to wear.

Osmium also has a very high refractive index, making it useful in optical applications such as in the production of pen tips and phonograph needles.

Osmium is known for its blue-gray tint, which is used in fountain pen inks, and for its toxicity, which has limited its use in certain applications such as jewelry making.

Applications

Alloys

Osmium is often used as an alloying agent with other metals to increase their hardness, corrosion resistance, and other properties. For example, it is added to platinum to make an alloy that is used in the production of fountain pen nibs, electrical contacts, and other high-wear applications.

Catalysts

Osmium compounds are used as catalysts in a variety of chemical reactions, such as asymmetric dihydroxylation of alkenes and the conversion of alkenes to aldehydes or ketones.

Electronics

Osmium is used in some electronic applications, such as in the production of thin-film resistors and in the manufacture of electrical contacts.

Medicine

Osmium compounds have shown promise in the treatment of cancer and other diseases. For example, osmium tetroxide is used in microscopy as a stain for biological tissues, and osmium-based compounds have been developed as potential anticancer agents.

Jewelry

Osmium is one of the densest elements and has a bluish-gray color, making it a popular choice for jewelry. However, due to its rarity and difficulty in processing, osmium jewelry is quite expensive.

Interesting facts

Osmium is the densest naturally occurring element, with a density of 22.59 g/cm3.

It has a blue-gray tint and is brittle at room temperature, but becomes ductile when it is slightly heated.

Osmium is one of the rarest elements on Earth, with only about 50 tons mined each year, primarily from South Africa, Russia, and Canada.

Osmium is also one of the most toxic elements known, and its tetroxide compound is particularly dangerous, as it can cause severe eye and lung damage or even death.

Despite its toxicity, osmium has found some niche applications, such as in the manufacturing of fountain pen tips, phonograph needles, and electrical contacts, as well as in some medical procedures.

Osmium is also used in some alloys, such as osmiridium, which is a hard and durable material used in some high-end watches and jewelry.

Related

More elements

s block
p block
d block
f block
Barium Aluminium Bohrium Actinium
Beryllium Antimony Cadmium Americium
Caesium Argon Chromium Berkelium
Calcium Arsenic Cobalt Californium
Francium Astatine Copernicium Cerium
Helium Bismuth Copper Curium
Hydrogen Boron Darmstadtium Dysprosium
Lithium Bromine Dubnium Einsteinium
Magnesium Carbon Gold Erbium
Potassium Chlorine Hafnium Europium
Radium Flerovium Hassium Fermium
Rubidium Fluorine Iridium Gadolinium
Sodium Gallium Iron Holmium
Strontium Germanium Lawrencium Lanthanum
Indium Lutetium Mendelevium
Iodine Manganese Neodymium
Krypton Meitnerium Neptunium
Lead Mercury Nobelium
Livermorium Molybdenum Plutonium
Moscovium Nickel Praseodymium
Neon Niobium Promethium
Nihonium Osmium Protactinium
Nitrogen Palladium Samarium
Oganesson Platinum Terbium
Oxygen Rhenium Thorium
Phosphorus Rhodium Thulium
Polonium Roentgenium Uranium
Radon Ruthenium Ytterbium
Selenium Rutherfordium
Silicon Scandium
Sulfur Seaborgium
Tellurium Silver
Tennessine Tantalum
Thallium Technetium
Tin Titanium
Xenon Tungsten
Vanadium
Yttrium
Zinc
Zirconium

External links

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Learnool.com was founded by Deep Rana, who is a mechanical engineer by profession and a blogger by passion. He has a good conceptual knowledge on different educational topics and he provides the same on this website. He loves to learn something new everyday and believes that the best utilization of free time is developing a new skill.

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