Ruthenium

Ruthenium
Ruthenium block | Image: Learnool

Ruthenium (Ru) is a chemical element of the periodic table, located in the group 8 and the period 5, and has the atomic number 44. It is a hard, brittle, rare, lustrous, silvery-white transition metal, which is named after Ruthenia, the Latin name for Russia.

On periodic table

group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
period
1 1
H
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Hydrogen
2
He
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Helium
2 3
Li
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Lithium
4
Be
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Beryllium
5
B
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Boron
6
C
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Carbon
7
N
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Nitrogen
8
O
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Oxygen
9
F
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Fluorine
10
Ne
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Neon
3 11
Na
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Sodium
12
Mg
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Magnesium
13
Al
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Aluminium
14
Si
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Silicon
15
P
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Phosphorus
16
S
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Sulfur
17
Cl
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Chlorine
18
Ar
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Argon
4 19
K
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Potassium
20
Ca
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Calcium
21
Sc
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Scandium
22
Ti
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Titanium
23
V
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Vanadium
24
Cr
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Chromium
25
Mn
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Manganese
26
Fe
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Iron
27
Co
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Cobalt
28
Ni
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Nickel
29
Cu
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Copper
30
Zn
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Zinc
31
Ga
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Gallium
32
Ge
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Germanium
33
As
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Arsenic
34
Se
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Selenium
35
Br
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Bromine
36
Kr
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Krypton
5 37
Rb
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Rubidium
38
Sr
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Strontium
39
Y
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Yttrium
40
Zr
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Zirconium
41
Nb
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Niobium
42
Mo
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Molybdenum
43
Tc
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Technetium
44
Ru
Ruthenium
45
Rh
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Rhodium
46
Pd
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Palladium
47
Ag
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Silver
48
Cd
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Cadmium
49
In
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Indium
50
Sn
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Tin
51
Sb
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Antimony
52
Te
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Tellurium
53
I
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Iodine
54
Xe
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Xenon
6 55
Cs
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Caesium
56
Ba
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Barium
72
Hf
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Hafnium
73
Ta
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Tantalum
74
W
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Tungsten
75
Re
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Rhenium
76
Os
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Osmium
77
Ir
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Iridium
78
Pt
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Platinum
79
Au
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Gold
80
Hg
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Mercury
81
Tl
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Thallium
82
Pb
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Lead
83
Bi
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Bismuth
84
Po
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Polonium
85
At
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Astatine
86
Rn
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Radon
7 87
Fr
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Francium
88
Ra
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Radium
104
Rf
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Rutherfordium
105
Db
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Dubnium
106
Sg
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Seaborgium
107
Bh
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Bohrium
108
Hs
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Hassium
109
Mt
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Meitnerium
110
Ds
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Darmstadtium
111
Rg
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Roentgenium
112
Cn
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Copernicium
113
Nh
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Nihonium
114
Fl
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Flerovium
115
Mc
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Moscovium
116
Lv
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Livermorium
117
Ts
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Tennessine
118
Og
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Oganesson
57
La
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Lanthanum
58
Ce
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Cerium
59
Pr
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Praseodymium
60
Nd
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Neodymium
61
Pm
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Promethium
62
Sm
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Samarium
63
Eu
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Europium
64
Gd
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Gadolinium
65
Tb
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Terbium
66
Dy
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Dysprosium
67
Ho
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Holmium
68
Er
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Erbium
69
Tm
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Thulium
70
Yb
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Ytterbium
71
Lu
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Lutetium
89
Ac
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Actinium
90
Th
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Thorium
91
Pa
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Protactinium
92
U
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Uranium
93
Np
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Neptunium
94
Pu
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Plutonium
95
Am
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Americium
96
Cm
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Curium
97
Bk
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Berkelium
98
Cf
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Californium
99
Es
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Einsteinium
100
Fm
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Fermium
101
Md
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Mendelevium
102
No
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Nobelium
103
Lr
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Lawrencium
– d block

Ruthenium is a d-block element, situated in the eighth column and the fifth row of the periodic table, denoted by the atomic number 44 and chemical symbol Ru.

Element information

Ruthenium element
SymbolRu
Atomic number (Z)44
Standard atomic weight101.07
CAS number7440-18-8
Origin of nameFrom Latin Ruthenia, a historical name for Russia
Group8
Period5
Blockd
ClassificationTransition metal
Electron configuration[Kr] 4d7 5s1
Electrons per shell2, 8, 18, 15, 1
Valence electrons8
Protons, neutrons, electrons44 protons, 57 neutrons, 44 electrons (for most common isotope: 102Ru)
Learn how to find: Ruthenium protons neutrons electrons
Oxidation state(s)+2, +3, +4, +6, +8
Electronegativity (Pauling scale)2.2
Atomic radius134 pm
Covalent radius150 pm
Van der Waals radiusNot well-defined
Phase at room temperatureSolid
Crystal structureHexagonal close-packed (hcp)
Density near room temperature12.45 g/cm3
Melting point2,334 °C
Boiling point4,150 °C
Main isotopes99Ru, 100Ru, 102Ru, 104Ru, 106Ru
Natural occurrencePrimordial
Discovered byKarl Ernst Claus, 1844

History

Karl Ernst Claus | Image: Wikipedia

Ruthenium was discovered by a Russian chemist named Karl Klaus in 1844. Klaus was studying platinum ores from the Ural Mountains when he discovered a small amount of a new element that he named “ruthenium” after Ruthenia, the Latin word for Russia. The discovery was later confirmed by another Russian chemist named Gottfried Osann.

However, it was not until 1860 that the element was isolated in pure form by the German chemist Karl Ernst Claus, who was able to obtain a few grams of the metal by reducing its oxide with hydrogen gas. Since then, ruthenium has been identified as a rare and valuable element with important applications in industry, electronics, and catalysis.

Occurrence and production

Ruthenium is a rare transition metal that occurs naturally in the Earth’s crust at very low concentrations, typically in ores containing platinum group metals. The largest deposits of ruthenium are found in the Ural Mountains of Russia, although it is also found in smaller quantities in North and South America, as well as in other parts of the world. The main sources of ruthenium are sulfide and platinum group metal ores, with production typically achieved as a by-product of refining these ores.

The production of ruthenium is a complex and multistage process that involves several steps, including mining, concentration, smelting, and refining. The first step involves the extraction of the ore from the ground, typically through underground or open-pit mining. The next step is concentration, in which the ore is processed to remove impurities and increase the concentration of ruthenium. This is typically achieved through froth flotation, a process in which the ore is mixed with water and chemicals that cause the desired minerals to float to the top.

The concentrated ore is then smelted to remove any remaining impurities and to separate the various metals contained within it. This process typically involves heating the ore in a furnace with a reducing agent, such as carbon, which reacts with the oxygen in the ore to form carbon dioxide and leave behind the desired metal. The resulting metal is then further refined through a process of chemical purification, typically involving the use of solvents or electrolysis, to produce high-purity ruthenium.

Properties

Ruthenium is a hard, silvery-white metal that belongs to the platinum group of elements.

It has a high melting point of 2334 ℃ and a boiling point of 4150 ℃.

Ruthenium is a rare and expensive metal, with an abundance in the Earth’s crust of only about 0.001 ppm.

It is a good conductor of electricity and has excellent resistance to corrosion and oxidation.

Ruthenium has a density of 12.45 g/cm3 and is one of the densest elements known.

It is mainly produced as a byproduct of platinum mining and refining.

Ruthenium exists in several oxidation states, with the most common being +2 and +4.

It forms many compounds, including ruthenium oxide, ruthenium chloride, and ruthenium nitrosyl complexes.

Ruthenium has important applications in various industries, including electronics, catalysis, and solar energy conversion.

It is also used in the production of hard disk drives, dental implants, and as a catalyst in organic chemical reactions.

Applications

Catalysis

Ruthenium is widely used as a catalyst in various chemical reactions, including hydrogenation, oxidation, and isomerization.

Its unique chemical and physical properties make it an ideal catalyst in many industrial processes, such as the production of fertilizers, petrochemicals, and pharmaceuticals.

Electronics

Ruthenium is used in the production of electronic components, such as resistors, capacitors, and hard disk drives. It is also used as a conductor in microelectronics and as a coating material in optical devices.

Jewelry

Ruthenium has a unique dark-gray color, which makes it an attractive material for jewelry. It is used as a plating material on white gold and other precious metals to improve their durability and resistance to wear and tear.

Medical applications

Ruthenium compounds have shown promising results in the treatment of cancer. They are used as anticancer agents and as imaging agents in diagnostic tests.

Solar energy

Ruthenium is used in the production of solar cells, where it acts as a photosensitizer, converting light into electricity.

Batteries

Ruthenium is used in the production of rechargeable batteries, where it acts as a cathode material.

Ruthenium-based batteries have high energy density and long cycle life, making them suitable for various applications, such as electric vehicles and portable electronic devices.

Interesting facts

Ruthenium is one of the rarest metals in the Earth’s crust, with an abundance of only 0.001 ppm.

The name “ruthenium” comes from “Ruthenia,” the Latin word for Russia, where the element was discovered.

Ruthenium is the fourth densest metal, following osmium, iridium, and platinum.

It has a unique ability to form a stable oxide layer, which makes it highly resistant to corrosion and oxidation.

Ruthenium is used as a catalyst in many important industrial processes, including the production of fertilizers and synthetic materials.

It has potential applications in cancer treatment, as ruthenium compounds have shown promise in destroying cancer cells.

Ruthenium is also used in the production of hard disk drives, where it is used to coat the platters to improve their magnetic properties.

In 2018, a team of scientists created the world’s smallest electric motor using a single ruthenium atom.

Related

More elements

External links

Deep

Learnool.com was founded by Deep Rana, who is a mechanical engineer by profession and a blogger by passion. He has a good conceptual knowledge on different educational topics and he provides the same on this website. He loves to learn something new everyday and believes that the best utilization of free time is developing a new skill.

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