Thulium

Thulium
Thulium block | Image: Learnool

Thulium (Tm) is a chemical element of the periodic table, located in the period 6, and has the atomic number 69. It is the thirteenth element in the lanthanide series. It is a bright, silvery-gray metal, whose name comes from “Thule”, the ancient name for Scandinavia. It is not available freely in nature and is counted as one of the rare earth elements.

On periodic table

group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
period
1 1
H
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Hydrogen
2
He
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Helium
2 3
Li
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Lithium
4
Be
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Beryllium
5
B
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Boron
6
C
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Carbon
7
N
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Nitrogen
8
O
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Oxygen
9
F
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Fluorine
10
Ne
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Neon
3 11
Na
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Sodium
12
Mg
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Magnesium
13
Al
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Aluminium
14
Si
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Silicon
15
P
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Phosphorus
16
S
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Sulfur
17
Cl
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Chlorine
18
Ar
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Argon
4 19
K
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Potassium
20
Ca
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Calcium
21
Sc
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Scandium
22
Ti
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Titanium
23
V
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Vanadium
24
Cr
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Chromium
25
Mn
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Manganese
26
Fe
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Iron
27
Co
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Cobalt
28
Ni
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Nickel
29
Cu
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Copper
30
Zn
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Zinc
31
Ga
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Gallium
32
Ge
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Germanium
33
As
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Arsenic
34
Se
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Selenium
35
Br
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Bromine
36
Kr
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Krypton
5 37
Rb
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Rubidium
38
Sr
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Strontium
39
Y
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Yttrium
40
Zr
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Zirconium
41
Nb
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Niobium
42
Mo
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Molybdenum
43
Tc
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Technetium
44
Ru
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Ruthenium
45
Rh
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Rhodium
46
Pd
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Palladium
47
Ag
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Silver
48
Cd
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Cadmium
49
In
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Indium
50
Sn
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Tin
51
Sb
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Antimony
52
Te
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Tellurium
53
I
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Iodine
54
Xe
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Xenon
6 55
Cs
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Caesium
56
Ba
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Barium
72
Hf
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Hafnium
73
Ta
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Tantalum
74
W
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Tungsten
75
Re
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Rhenium
76
Os
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Osmium
77
Ir
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Iridium
78
Pt
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Platinum
79
Au
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Gold
80
Hg
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Mercury
81
Tl
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Thallium
82
Pb
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Lead
83
Bi
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Bismuth
84
Po
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Polonium
85
At
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Astatine
86
Rn
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Radon
7 87
Fr
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Francium
88
Ra
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Radium
104
Rf
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Rutherfordium
105
Db
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Dubnium
106
Sg
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Seaborgium
107
Bh
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Bohrium
108
Hs
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Hassium
109
Mt
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Meitnerium
110
Ds
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Darmstadtium
111
Rg
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Roentgenium
112
Cn
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Copernicium
113
Nh
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Nihonium
114
Fl
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Flerovium
115
Mc
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Moscovium
116
Lv
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Livermorium
117
Ts
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Tennessine
118
Og
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Oganesson
57
La
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Lanthanum
58
Ce
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Cerium
59
Pr
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Praseodymium
60
Nd
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Neodymium
61
Pm
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Promethium
62
Sm
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Samarium
63
Eu
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Europium
64
Gd
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Gadolinium
65
Tb
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Terbium
66
Dy
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Dysprosium
67
Ho
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Holmium
68
Er
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Erbium
69
Tm
Thulium
70
Yb
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Ytterbium
71
Lu
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Lutetium
89
Ac
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Actinium
90
Th
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Thorium
91
Pa
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Protactinium
92
U
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Uranium
93
Np
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Neptunium
94
Pu
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Plutonium
95
Am
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Americium
96
Cm
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Curium
97
Bk
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Berkelium
98
Cf
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Californium
99
Es
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Einsteinium
100
Fm
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Fermium
101
Md
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Mendelevium
102
No
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Nobelium
103
Lr
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Lawrencium
– f block

Thulium (Tm) is located on the periodic table in the lanthanide series, which is a group of elements located at the bottom of the table. Specifically, in period 6, between erbium (Er) and ytterbium (Yb).

Element information

Thulium element
SymbolTm
Atomic number (Z)69
Standard atomic weight168.93422
CAS number7440-30-4
Origin of nameFrom Thule, a mythical northern land
GroupLanthanide
Period6
Blockf
ClassificationLanthanide
Electron configuration[Xe] 4f13 6s2
Learn how to write: Thulium electron configuration
Electrons per shell2, 8, 18, 31, 8, 2
Valence electrons3
Protons, neutrons, electrons69 protons, 100 neutrons, 69 electrons (for most common isotope: 169Tm)
Oxidation state(s)+3
Electronegativity (Pauling scale)1.25
Atomic radius174 pm
Covalent radius190 pm
Van der Waals radiusNot well-defined
Phase at room temperatureSolid
Crystal structureHexagonal close-packed (hcp)
Density near room temperature9.32 g/cm3
Melting point1,545 °C
Boiling point1,950 °C
Main isotopes169Tm
Natural occurrencePrimordial; rarest stable lanthanide
Discovered byPer Teodor Cleve, 1879

History

Per Teodor Cleve | Image: Wikipedia

Thulium was discovered in 1879 by the Swedish chemist Per Teodor Cleve. Cleve was analyzing the mineral erbia, which is primarily composed of erbium oxide, and observed that a new substance was present in the sample. He named the new element thulium after the ancient name for Scandinavia, Thule. Thulium was the last of the rare earth elements to be discovered, and its discovery completed the series of 15 elements from lanthanum to lutetium. The development of spectroscopic techniques in the late 19th century was crucial to the discovery of thulium and the other rare earth elements, as it allowed scientists to distinguish between the different elements based on the unique spectra they produced. Thulium is still relatively rare and not widely used, but its unique properties make it an important element for certain applications.

Occurrence and production

Thulium is a rare earth element that is relatively abundant in the earth’s crust. It is found in several minerals such as monazite, xenotime, and euxenite. Monazite sands, which are rich in rare earth elements including thulium, are the primary source for thulium production. Thulium can be extracted from these minerals using a process called ion exchange or solvent extraction. The process involves extracting rare earth elements using an organic solvent that selectively binds with specific rare earth elements. Once extracted, the thulium is then purified using several refining techniques including precipitation, ion exchange, and fractional crystallization. Thulium is a rare earth element and is therefore difficult and expensive to produce. The annual worldwide production of thulium is estimated to be around 50 to 60 tonnes per year.

Properties

Thulium is the second least abundant of the rare earth elements, with an abundance in the Earth’s crust estimated to be about 0.5 parts per million.

It is a relatively soft metal, with a hardness similar to that of lead.

Thulium has a melting point of 1545 ℃ (2813 ℉) and a boiling point of 1950 ℃ (3542 ℉).

It has a high electrical resistivity, making it useful for certain types of electrical components.

Thulium has the highest magnetic moment of any naturally occurring element, which makes it useful for magnetic resonance imaging (MRI) and other medical applications.

It has a unique fluorescence spectrum that makes it useful in fiber-optic amplifiers, which are used in telecommunications.

Applications

Nuclear energy

Thulium-170 is used as a neutron source in nuclear reactors for research purposes. When thulium-170 is bombarded with neutrons, it produces a radioactive isotope that can be used for imaging and radiation therapy in medical applications.

Fiber optic amplifiers

Thulium-doped fiber optic amplifiers are used in telecommunications for signal amplification over long distances. These amplifiers can boost the power of optical signals traveling through fiber optic cables, allowing for faster and more reliable communication.

Portable X-ray machines

Thulium is used as a radiation source in portable X-ray machines, which are commonly used in the field by doctors, veterinarians, and other healthcare professionals. These machines can be particularly useful in remote or underserved areas, where access to traditional X-ray equipment may be limited.

High-temperature superconductors

Thulium is used in high-temperature superconductors, which have important applications in fields such as energy storage and transportation. Superconductors made with thulium can conduct electricity with zero resistance at higher temperatures than other materials, making them more practical for use in real-world applications.

Magnets

Thulium is used to create high-strength magnets that have applications in fields such as aerospace and defense. These magnets can be used in motors, generators, and other devices that require strong magnetic fields.

Interesting facts

Thulium is named after the ancient city of Thule in Scandinavia, which is believed to be located in modern-day Norway.

Thulium is one of the least abundant rare earth elements, with an abundance in the Earth’s crust of about 0.5 parts per million.

Thulium has a relatively low melting point of 1545 ℃, which is the second-lowest of all the rare earth metals after europium.

Thulium is the second-least reactive of all the rare earth metals, after lutetium.

Thulium emits X-rays when exposed to gamma rays, which makes it useful for medical imaging and radiation therapy.

Thulium has the highest magnetic moment of all the rare earth elements, which makes it useful for making magnets.

Thulium-doped fibers are used in high-power fiber optic amplifiers, which are used to boost the signal strength of long-distance communication cables.

Related

More elements

External links

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Learnool.com was founded by Deep Rana, who is a mechanical engineer by profession and a blogger by passion. He has a good conceptual knowledge on different educational topics and he provides the same on this website. He loves to learn something new everyday and believes that the best utilization of free time is developing a new skill.

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