Barium

Barium
Barium block | Image: Learnool

Barium (Ba) is a chemical element of the periodic table, located in the group 2 and the period 6, and has the atomic number 56. It is a soft, silvery-white alkaline earth metal, whose name comes from the Greek word “barys”, which means heavy. It is a highly reactive metal that is not available freely in nature.

On periodic table

group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
period
1 1
H
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Hydrogen
2
He
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Helium
2 3
Li
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Lithium
4
Be
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Beryllium
5
B
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Boron
6
C
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Carbon
7
N
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Nitrogen
8
O
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Oxygen
9
F
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Fluorine
10
Ne
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Neon
3 11
Na
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Sodium
12
Mg
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Magnesium
13
Al
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Aluminium
14
Si
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Silicon
15
P
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Phosphorus
16
S
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Sulfur
17
Cl
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Chlorine
18
Ar
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Argon
4 19
K
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Potassium
20
Ca
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Calcium
21
Sc
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Scandium
22
Ti
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Titanium
23
V
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Vanadium
24
Cr
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Chromium
25
Mn
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Manganese
26
Fe
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Iron
27
Co
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Cobalt
28
Ni
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Nickel
29
Cu
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Copper
30
Zn
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Zinc
31
Ga
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Gallium
32
Ge
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Germanium
33
As
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Arsenic
34
Se
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Selenium
35
Br
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Bromine
36
Kr
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Krypton
5 37
Rb
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Rubidium
38
Sr
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Strontium
39
Y
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Yttrium
40
Zr
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Zirconium
41
Nb
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Niobium
42
Mo
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Molybdenum
43
Tc
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Technetium
44
Ru
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Ruthenium
45
Rh
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Rhodium
46
Pd
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Palladium
47
Ag
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Silver
48
Cd
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Cadmium
49
In
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Indium
50
Sn
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Tin
51
Sb
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Antimony
52
Te
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Tellurium
53
I
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Iodine
54
Xe
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Xenon
6 55
Cs
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Caesium
56
Ba
Barium
72
Hf
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Hafnium
73
Ta
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Tantalum
74
W
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Tungsten
75
Re
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Rhenium
76
Os
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Osmium
77
Ir
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Iridium
78
Pt
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Platinum
79
Au
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Gold
80
Hg
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Mercury
81
Tl
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Thallium
82
Pb
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Lead
83
Bi
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Bismuth
84
Po
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Polonium
85
At
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Astatine
86
Rn
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Radon
7 87
Fr
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Francium
88
Ra
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Radium
104
Rf
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Rutherfordium
105
Db
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Dubnium
106
Sg
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Seaborgium
107
Bh
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Bohrium
108
Hs
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Hassium
109
Mt
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Meitnerium
110
Ds
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Darmstadtium
111
Rg
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Roentgenium
112
Cn
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Copernicium
113
Nh
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Nihonium
114
Fl
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Flerovium
115
Mc
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Moscovium
116
Lv
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Livermorium
117
Ts
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Tennessine
118
Og
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Oganesson
57
La
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Lanthanum
58
Ce
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Cerium
59
Pr
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Praseodymium
60
Nd
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Neodymium
61
Pm
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Promethium
62
Sm
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Samarium
63
Eu
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Europium
64
Gd
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Gadolinium
65
Tb
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Terbium
66
Dy
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Dysprosium
67
Ho
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Holmium
68
Er
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Erbium
69
Tm
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Thulium
70
Yb
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Ytterbium
71
Lu
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Lutetium
89
Ac
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Actinium
90
Th
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Thorium
91
Pa
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Protactinium
92
U
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Uranium
93
Np
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Neptunium
94
Pu
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Plutonium
95
Am
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Americium
96
Cm
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Curium
97
Bk
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Berkelium
98
Cf
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Californium
99
Es
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Einsteinium
100
Fm
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Fermium
101
Md
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Mendelevium
102
No
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Nobelium
103
Lr
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Lawrencium
– s block

Barium is an s-block element, situated in the second column and the sixth row of the periodic table, denoted by the atomic number 56 and chemical symbol Ba.

Element information

Barium element
SymbolBa
Atomic number (Z)56
Standard atomic weight137.327
CAS number7440-39-3
Origin of nameFrom Greek barys, meaning “heavy”
Group2
Period6
Blocks
ClassificationAlkaline earth metal
Electron configuration[Xe] 6s2
Learn how to write: Barium electron configuration
Electrons per shell2, 8, 18, 18, 8, 2
Learn how to draw: Barium Bohr model
Valence electrons2
Learn how to find: Barium valence electrons
Protons, neutrons, electrons56 protons, 81 neutrons, 56 electrons (for most common isotope: 137Ba)
Learn how to find: Barium protons neutrons electrons
Oxidation state(s)+2
Electronegativity (Pauling scale)0.89
Atomic radius253 pm
Covalent radius215 pm
Van der Waals radius268 pm
Phase at room temperatureSolid
Crystal structureBody-centered cubic (bcc)
Density near room temperature3.62 g/cm3
Melting point727 °C
Boiling point1,897 °C
Main isotopes134Ba, 136Ba, 137Ba, 138Ba
Natural occurrencePrimordial; found in barite and witherite
Discovered byCarl Wilhelm Scheele, 1772 (isolated by Humphry Davy, 1808)

History

Carl Wilhelm Scheele | Image: Britannica

Barium has been known since ancient times due to its occurrence in mineral deposits, but its discovery as a distinct element dates back to the late 18th century. In 1774, Carl Wilhelm Scheele, a Swedish chemist, identified barium oxide and noted its similarity to lime. However, he did not realize that the two substances were different elements.

In 1808, Sir Humphry Davy, an English chemist, conducted electrolysis experiments on molten barium salts and succeeded in isolating pure barium metal. He named the new element barium, after the Greek word “barys,” meaning heavy, due to its high atomic weight.

In the early 19th century, barium compounds were used in the textile industry to manufacture black and green dyes. They were also used in medicine as a laxative and as a contrast agent in X-ray imaging. The bright green color of barium compounds made them popular for use in fireworks, and this application continues today.

During the 20th century, barium continued to be used in medicine, especially in diagnostic imaging techniques such as barium enemas and barium meals. Barium was also used in the manufacture of vacuum tubes for electronic equipment, and as a deoxidizer in the production of aluminum alloys. Today, barium is still used in a variety of applications, including in the production of ceramic and glass materials, in the petroleum industry, and in the production of rubber products.

Occurrence and production

Barium is a relatively abundant element on Earth, with an estimated concentration of 425 ppm in the Earth’s crust. It occurs naturally in the minerals barite (BaSO4) and witherite (BaCO3), and can also be found in some mineral springs. The majority of commercial production of barium compounds involves the extraction of barite, which is typically done through mining. The largest commercial producers of barite are China, India, and Morocco. The extracted ore is then crushed and ground to produce a fine powder, which is then subjected to a series of chemical treatments to purify and concentrate the barium.

The primary method for producing metallic barium involves the reduction of barium oxide (BaO) with aluminum metal at high temperatures. This produces barium vapor, which is condensed into a solid form. Another method for producing barium involves the electrolysis of molten barium chloride (BaCl2) using a mercury cathode. This produces elemental barium and chlorine gas as byproducts. However, this method is less commonly used due to the high cost of production and safety concerns associated with handling mercury.

Properties

Barium is a soft, silvery-white metal that oxidizes quickly in air.

It has a melting point of 727 ℃ and a boiling point of 1845 ℃.

Barium is a highly reactive metal that can react with water or other chemicals to produce potentially hazardous gases, such as hydrogen gas or ammonia gas.

It is a good conductor of electricity and has a relatively low density.

Barium is an alkaline earth metal, which means it has similar properties to other elements in this group, such as calcium and magnesium.

It can form a variety of chemical compounds, including barium sulfate (BaSO4), barium chloride (BaCl2), and barium nitrate [Ba(NO3)2].

Applications

Medicine

Barium sulfate is used as a contrast medium in medical imaging procedures such as X-rays and CT scans. It helps to highlight the digestive tract and gastrointestinal system to aid in diagnosis.

Fireworks

Green fireworks are created using barium | Image: Phantom Fireworks

Barium is commonly used in pyrotechnics to produce bright green colors in fireworks. This is due to the emission of green light when barium compounds are heated.

Petroleum industry

Barium is used in the petroleum industry to increase the density of drilling mud. Barium sulfate is added to the mud to help control pressure and prevent blowouts during drilling.

Electronics

Barium titanate is a ceramic material that exhibits ferroelectric properties and is used in the manufacture of capacitors, varistors, and other electronic components.

Glass industry

Barium is used in the glass industry to improve the refractive index and durability of glass. Barium oxide is added to the glass mixture to enhance its chemical and thermal resistance.

Agriculture

Barium is an essential micronutrient for some plants, and deficiency can lead to stunted growth and poor yields. Barium sulfate is also used in animal feed as a filler and source of dietary sulfate.

Interesting facts

Barium has a unique property of being able to absorb X-rays, which makes it useful in medical imaging such as X-ray and CT scans.

The name barium comes from the Greek word “barys” which means heavy.

Barium is a highly reactive element and must be stored in oil or kerosene to prevent it from reacting with air or water.

Barium is used in the production of various types of glass, including cathode ray tubes, which are used in televisions and computer monitors.

When burned, barium emits a bright green light, which is why it is used in fireworks and flares.

Barium compounds are used in the petroleum industry to increase the density of drilling fluids, which helps to prevent blowouts.

Barium sulfate is often used as a contrast agent in medical tests such as barium swallows and barium enemas.

Barium carbonate has been used for centuries as a rat poison, although it is now largely prohibited due to its toxicity.

Related

More elements

External links

Deep

Learnool.com was founded by Deep Rana, who is a mechanical engineer by profession and a blogger by passion. He has a good conceptual knowledge on different educational topics and he provides the same on this website. He loves to learn something new everyday and believes that the best utilization of free time is developing a new skill.

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